原文：https://doi.org/10.1016/j.jechem.2021.04.040
Abstract:
We report the growth of high-quality lead-free molecular 1D perovskite [(CH3)3NH]MnCl32H2O single crystal with size aslarge as 5 x 20 x 2 mm³ and demonstrate its potential for efficient X-ray detection. The 1D [(CH₃)₃NH]MnCl₃·2H₂O single crystal can be achieved from aqueous solution at room temperature using seed crystallization method. The crystal packing, optical properties,
band nature, charge transport properties and optoelectronic application as efficient X-ray detection of the high-quality crystal are systemically studied. Due to its superior charge mobility and lifetime product (6.77x10^-3 cm² V^-1), the crystal device delivers a high sensitivity of 295 mC Gy_air^-1 cm^-2 at 50 V and a low detection limit (0.90 Gy_air s^-1 at 50 V).